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We consider nearly-integrable Hamiltonian systems defined over a non resonant domain. In the neighborhood of resonances, we use Nekhoroshev-like estimates to provide effective stability bounds for the action variables over long times. The applicability conditions of these estimates allow some freedom in the choice of parameters. Hence, we develop an optimization algorithm for choosing parameters that maximize the stability time. To further improve the stability estimates, we use perturbation theory to reduce the norm of the perturbing function. We implement this procedure (effective stability estimates and perturbation theory) to analyze the stability of sequences of irrational (Diophantine) frequencies converging to frequencies corresponding to resonances. We consider two applications to models describing problems of rotational dynamics in Celestial Mechanics: the spin-orbit problem, described by a 1D time-dependent Hamiltonian, and the spin-spin-orbit model, described by a 2D time-dependent Hamiltonian. We show stability results for orbits close to the main resonances associated to such models.